It will begin the activity in September, in a drive to avoid a repeat of the guerrilla marketing tactics seen at the last FIFA World Cup.
Some experts believe that ambush marketing will hit unprecedented levels during the Games, as rivals of sponsors try to benefit from the event.
Sources have told Marketing the activity is likely to run across print, online, direct and outdoor.
Central to the campaign will be educating stakeholders and the wider business community on the new rules on ambush marketing, which will soon become law. Brands that break the rules could face court.
It is thought LOCOG, with law firm Freshfields, has briefed brands and sponsorship agencies on the subject.
Tier one - Adidas, BMW, BP, British Airways, BT, EDF, Lloyds TSB
Tier two - Adecco, ArcelorMittal, Cadbury, Cisco, Deloitte, Thomas Cook, UPS
Tier three - Aggreko, Airwave, Atkins, The Boston Consulting Group, CBS Outdoor, Crystal CG, Eurostar, Freshfields Bruckhaus Deringer LLP, G4S, GlaxoSmith-Kline, Gymnova, Heineken UK, Holiday Inn, John Lewis, McCann Worldgroup, Mondo, Next, The Nielsen Company, Populous, Rapiscan Systems, Rio Tinto, Technogym, Thames Water, Ticketmaster, Trebor