The services are aimed at small and medium-sized business or regional companies that have not advertised on TV previously.
Adshow will allow brands to create cost effective VoD ads and offers three templates to which advertisers can apply their own existing assets. Advertisers will be able to target campaigns by region, if desired.
Jon Block, ITV's head of commercial innovation, said: "We are delighted to be launching this new innovative format for VoD adverts and welcome a number of non-traditional TV brands and local businesses to ITV.
"Using Ad Show, we are now able to offer a wide-range of brands the opportunity to make their adverts relevant to our audiences in a new, modern, relevant and cost effective way."