The ad features a woman telling her scruffily dressed partner that her friends are about to arrive. He leaves the room and remerges as a well-dressed, better-looking version of himself, carrying a tray of the coffee drink.
The 30-second spot airs for the first time this weekend, during the ad break of the new series of ITV's 'Britain's Got Talent'.
The campaign runs for four weeks and will also appear on pre-roll from 2 April, across Sky, ITV, 4OD and other online video channels, with media bought by PHD.
Carte Noire returned to TV last year, after a nine-year hiatus. It launched the first execution of its 'Seductive' positioning in 2009, with a campaign called the 'The Carte Noire Readers', featuring Joseph Fiennes, Dominic West and Greg Wise, reading passages from Penguin fiction.
Kraft Foods has kicked off a review to create a digital roster across its brands, which include Dairylea, Cadbury and Oreo.
Follow Sarah Shearman on Twitter: @Shearmans